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Flying circus of physics

Physics for the first date --- wintergreen flashes

Monday, September 01, 2014

Physics for the first date --- wintergreen flashes
Jearl Walker  www.flyingcircusofphysics.com
September 2014   You and a friend first adapt your eyes to darkness for about 15 minutes in a closet or outside on a moonless night. Then have your friend chew a wintergreen LifeSaver candy (a candy in the shape of a marine lifesaver and infused with the oil of wintergreen) with the mouth as open as possible so that you can see inside. Why does each bite initially produce a faint flash of blue light, and why do later bites fail to produce the light? (If you don’t want to eat the candy, squeeze it with a pair of pliers until it fractures.) Recording the brief, faint emissions of light with a camera is tricky but here is a video that is pretty good.

https://www.youtube.com/watch?v=jYETxD4LWXI

Whenever a bite breaks one of the mint’s sugar crystals into pieces, the pieces will probably end up with different charges. Suppose a crystal breaks into pieces A and B, with A negatively charged and B positively charged.


Some of the electrons on A will then jump across the gap to reach B. Because air has moved into the gap after the crystal breaks, these electrons jump through air. Those that collide with nitrogen molecules in the air transfer energy to the molecules, exciting them. When the molecules de-excite, they emit in the ultraviolet range, which you cannot see. However, the wintergreen molecules on the surface of the candy pieces absorb ultraviolet light and then emit blue light, which you can see—it is the blue light coming from your friend’s mouth. This process of absorbing light in one wavelength range (here, in the ultraviolet) and then emitting light in a longer wavelength range (here, blue light) is called fluorescence, and the process of producing light by fracturing crystals is called triboluminesce. In this next video, sugar crystals are continuously crushed in a high-speed blender. When shot from overhead by a low-light camera, you see a luminous ring in the blender. As the larger crystals are broken up into smaller crystals, the light gradually fades.

https://www.youtube.com/watch?v=6Q9s13HHGsI

References
Dots · through ··· indicate level of difficulty
Journal reference style: author, journal, volume, pages (date)
Book reference style: author, title, publisher, date, pages
· Harvey, A History of Luminescence, American Philosophical Society (Philadelphia, Pennsylvania), 1957, Chapter 10
· Edwards Jr., H., and D. W. Edwards, (letter) “Wintergreen mints eschewed,” New England Journal of Medicine, 278, No. 18, 1024-1025 (2 May 1968)
· Walton, A. J., “Triboluminescence,” Advances in Physics, 26, No. 6, 887-948 (1977), see pages 904-907
··· Chandra, B. P., “Kinetics of triboluminescence in crystals,” Journal of Physics D: Applied Physics, 10, 1531-1538 (1977)
· Walton, A. J., “From sweetness to light,” Physics Bulletin, 29, 355-356 (1978)
· “Scraped crystals light up from inside,” New Scientist, 80, ?? (5 October 1978)
· Zink, J. I., “Triboluminescence,” Accounts of Chemical Research, 11, No. 8, 289-295 (August 1978)
· Angelos, R., J. I. Zink, and G. E. Hardy, “Triboluminescence spectroscopy of common candies,” Journal of Chemical Education, 56, No. 6, 413-414 (June 1979)
··· Chandra, B. P., and J. I. Zink, “Triboluminescence and the dynamics of crystal fracture,” Physical Review B, 21, No. 2, 816-826 (15 January 1980)
·· Chandra, B. P., and J. I. Zink, “Mechanical characteristics and mechanism of the triboluminescence of fluorescent molecular crystals,” Journal of Chemical Physics, 73, No. 12, 5933-5941 (15 December 1980)
· Zink, J. I., “Squeezing light out of crystals triboluminescence,” Naturwissenschaften, 68, 507-512 (1981)
· Sweeting, L. M., M. L. Cashel, M. Dott, J. M. Gingerich, J. L. Guido, J. A. Kling, R. F. Pippin III, M. M. Rosenblatt, A. M. Rutter, and R. A. Spence, “Spectroscopy and mechanism in triboluminescence,” Molecular Crystals and Liquid Crystals, 211, 389-396 (1992)
··· Dickinson, J. T., S. C. Langford, and L. C. Jensen, "Recombination on fractal networks: photon and electron emission following fraction of materials," Journal of Materials Research, 8, No. 11, 2921-2932 (November 1993)
· Lea, A., and D. Fell, (letters) “Tonic blues,” New Scientist, 165, No. 2224, inside back cover (6 February 2000)
· Sweeting, L. M., “Triboluminescence with and without air,” Chem. Mater, 13, 854-870 (2001)
·· Eddingsaas, N. C., and K. S. Suslick, “Light from sonication of crystal slurries,” Nature, 444, 163 (9 November 2006)

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